{"id":2661,"date":"2014-04-16T14:58:30","date_gmt":"2014-04-16T12:58:30","guid":{"rendered":"https:\/\/ospt.osi.lv\/?p=2661"},"modified":"2022-01-11T12:13:27","modified_gmt":"2022-01-11T10:13:27","slug":"copper-catalyzed-intermolecular-c-h-amination-of-heteroarenes","status":"publish","type":"post","link":"https:\/\/ospt.osi.lv\/copper-catalyzed-intermolecular-c-h-amination-of-heteroarenes\/","title":{"rendered":"12. Copper-Catalyzed Intermolecular C-H Amination of (Hetero)arenes via Transient Unsymmetrical lambda3-Iodanes"},"content":{"rendered":"<p>Sokolovs, I.; Lubriks, D.; Suna, E.\u00a0<cite>J. Am. Chem. Soc. <\/cite><strong>2014<\/strong>,\u00a0<em>136<\/em>, 6920\u20136928<em>.<\/em><\/p>\n<p>DOI: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja502174d\" target=\"_blank\" rel=\"noopener\">10.1021\/ja502174d<\/a><\/p>\n<p><!--more--><\/p>\n<p>Abstract<\/p>\n<p>A one-pot two-step method for intermolecular C\u2013H amination of electron-rich heteroarenes and arenes has been developed. The approach is based on a room-temperature copper-catalyzed regioselective reaction of the in situ formed unsymmetrical (hetero)aryl-\u03bb<sup>3<\/sup>-iodanes with a wide range of primary and secondary aliphatic amines and anilines.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Sokolovs, I.; Lubriks, D.; Suna, E.\u00a0J. Am. Chem. Soc. 2014,\u00a0136, 6920\u20136928. DOI: 10.1021\/ja502174d<\/p>\n","protected":false},"author":1,"featured_media":2662,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"image","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[16,46],"tags":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2661"}],"collection":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/comments?post=2661"}],"version-history":[{"count":1,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2661\/revisions"}],"predecessor-version":[{"id":3985,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2661\/revisions\/3985"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media\/2662"}],"wp:attachment":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media?parent=2661"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/categories?post=2661"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/tags?post=2661"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}