{"id":2670,"date":"2015-08-19T15:12:27","date_gmt":"2015-08-19T13:12:27","guid":{"rendered":"https:\/\/ospt.osi.lv\/?p=2670"},"modified":"2022-01-11T12:13:48","modified_gmt":"2022-01-11T10:13:48","slug":"diazonamide-synthetic-studies","status":"publish","type":"post","link":"https:\/\/ospt.osi.lv\/diazonamide-synthetic-studies\/","title":{"rendered":"15. Diazonamide Synthetic Studies. Reactivity of N-Unsubstituted Benzofuro[2,3-b]indolines"},"content":{"rendered":"<p>Mutule, I.; Kalnins, T.; Vedejs, E.; Suna, E. <em>Chem. Heterocycl. Comp.<\/em> <strong>2015<\/strong>, <em>51<\/em>, 613-620.<\/p>\n<p>DOI: <a href=\"http:\/\/link.springer.com\/article\/10.1007%2Fs10593-015-1749-7\" target=\"_blank\" rel=\"noopener\">10.1007\/s10593-015-1749-7<\/a><\/p>\n<p><!--more--><\/p>\n<h4>Abstract<\/h4>\n<p>Benzofuro[2,3-<em class=\"EmphasisTypeItalic \">b<\/em>]indolines undergo ring opening in the presence of base to generate 3<em class=\"EmphasisTypeItalic \">H<\/em>-indolines. The latter can rearrange into 3-arylindoles through an intramolecular transfer of the methoxycarbonyl moiety from quaternary carbon to oxygen of phenol. The intermediate 3<em class=\"EmphasisTypeItalic \">H<\/em>-indolines can be isolated upon DMAP-catalyzed <em class=\"EmphasisTypeItalic \">O<\/em>-acylation of the phenol moiety with Boc<sub>2<\/sub>O.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Mutule, I.; Kalnins, T.; Vedejs, E.; Suna, E. Chem. Heterocycl. Comp. 2015, 51, 613-620. DOI: 10.1007\/s10593-015-1749-7<\/p>\n","protected":false},"author":1,"featured_media":2671,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"image","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[16,42],"tags":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2670"}],"collection":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/comments?post=2670"}],"version-history":[{"count":1,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2670\/revisions"}],"predecessor-version":[{"id":3988,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2670\/revisions\/3988"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media\/2671"}],"wp:attachment":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media?parent=2670"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/categories?post=2670"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/tags?post=2670"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}