{"id":2679,"date":"2017-01-06T15:25:08","date_gmt":"2017-01-06T13:25:08","guid":{"rendered":"https:\/\/ospt.osi.lv\/?p=2679"},"modified":"2022-01-11T12:14:11","modified_gmt":"2022-01-11T10:14:11","slug":"development-of-a-chiral-dmap-catalyst-for-the-dynamic-kinetic-resolution-of-azole-hemiaminals","status":"publish","type":"post","link":"https:\/\/ospt.osi.lv\/development-of-a-chiral-dmap-catalyst-for-the-dynamic-kinetic-resolution-of-azole-hemiaminals\/","title":{"rendered":"18. Development of a Chiral DMAP Catalyst for the Dynamic Kinetic Resolution of Azole Hemiaminals"},"content":{"rendered":"<p>Kinens, A.; Sejejs, M.; Kamlet, A. S.; Piotrowski, D. W.; Vedejs, E.; Suna, E. <em>J. Org. Chem.<\/em> <strong>2017<\/strong>, <em>82<\/em>, 869\u2013886.<\/p>\n<p>DOI: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.joc.6b02955\" target=\"_blank\" rel=\"noopener\">10.1021\/acs.joc.6b02955<\/a><\/p>\n<p><!--more--><\/p>\n<h4>Abstract<\/h4>\n<p>A new catalyst for the dynamic kinetic resolution of azole hemiaminals has been developed using late-stage structural modifications of the <i>tert<\/i>-leucinol-derived chiral subunit of DMAP species.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Kinens, A.; Sejejs, M.; Kamlet, A. S.; Piotrowski, D. W.; Vedejs, E.; Suna, E. J. Org. Chem. 2017, 82, 869\u2013886. DOI: 10.1021\/acs.joc.6b02955<\/p>\n","protected":false},"author":1,"featured_media":2680,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"image","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[45,16],"tags":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2679"}],"collection":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/comments?post=2679"}],"version-history":[{"count":1,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2679\/revisions"}],"predecessor-version":[{"id":3991,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2679\/revisions\/3991"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media\/2680"}],"wp:attachment":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media?parent=2679"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/categories?post=2679"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/tags?post=2679"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}