{"id":2683,"date":"2017-09-13T15:29:59","date_gmt":"2017-09-13T13:29:59","guid":{"rendered":"https:\/\/ospt.osi.lv\/?p=2683"},"modified":"2022-01-11T12:14:59","modified_gmt":"2022-01-11T10:14:59","slug":"stereodivergent-synthesis-of-pseudotabersonine-alkaloids","status":"publish","type":"post","link":"https:\/\/ospt.osi.lv\/stereodivergent-synthesis-of-pseudotabersonine-alkaloids\/","title":{"rendered":"20. Stereodivergent Synthesis of Pseudotabersonine Alkaloids"},"content":{"rendered":"<p>Kazak, M.; Priede, M.; Shubin, K.; Bartrum, H. E.; Poisson, J.-F.; Suna, E. <em>Org. Lett.<\/em> <strong>2017<\/strong>, <em>19<\/em>, 5356\u20135359.<\/p>\n<p>DOI: <a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.7b02635\" target=\"_blank\" rel=\"noopener\">10.1021\/acs.orglett.7b02635<\/a><\/p>\n<p><!--more--><\/p>\n<h4>Abstract<\/h4>\n<p>An eight-step stereodivergent synthesis of enantiomerically pure (\u2212)-14-epi-pseudotabersonine and (+)-pseudotabersonine has been developed from a common <i>N<\/i>&#8211;<i>tert<\/i>-butanesulfinyl ketimine key intermediate.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Kazak, M.; Priede, M.; Shubin, K.; Bartrum, H. E.; Poisson, J.-F.; Suna, E. Org. Lett. 2017, 19, 5356\u20135359. DOI: 10.1021\/acs.orglett.7b02635<\/p>\n","protected":false},"author":1,"featured_media":2684,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"image","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[44,16,42],"tags":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2683"}],"collection":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/comments?post=2683"}],"version-history":[{"count":1,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2683\/revisions"}],"predecessor-version":[{"id":3993,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/2683\/revisions\/3993"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media\/2684"}],"wp:attachment":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media?parent=2683"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/categories?post=2683"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/tags?post=2683"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}