{"id":4046,"date":"2022-06-21T09:18:57","date_gmt":"2022-06-21T07:18:57","guid":{"rendered":"https:\/\/ospt.osi.lv\/?p=4046"},"modified":"2022-11-16T09:01:19","modified_gmt":"2022-11-16T07:01:19","slug":"electrochemistry-and-reactivity-of-chelation-stabilized-hypervalent-bromineiii-compounds","status":"publish","type":"post","link":"https:\/\/ospt.osi.lv\/electrochemistry-and-reactivity-of-chelation-stabilized-hypervalent-bromineiii-compounds\/","title":{"rendered":"40. Electrochemistry and Reactivity of Chelation-stabilized Hypervalent Bromine(III) Compounds"},"content":{"rendered":"<div class=\"wpb-content-wrapper\"><p>[vc_row][vc_column][vc_column_text]Mohebbati, N.; Sokolovs, i.; Woite, P.; L\u00f5kov, M.; Parman, E.; Ugandi, M.; Leito, I.; Roemelt, M.; Suna, E.; Francke, R.; <em>Chem-Eur. J.<\/em> <strong>2022<\/strong>,<em> 28, <\/em>e202200974.<\/p>\n<p>DOI: <a title=\"Electrochemistry and Reactivity of Chelation-stabilized Hypervalent Bromine(III) Compounds\" href=\"https:\/\/doi.org\/10.1002\/chem.202200974\" target=\"_blank\" rel=\"nofollow noopener\">10.1002\/chem.202200974<\/a><\/p>\n<p><!--more--><\/p>\n<h4>Abstract<\/h4>\n<p style=\"text-align: justify;\"><b>Despite their promising properties<\/b>, hypervalent bromine(III) reagents remain underexplored due to their low stability and difficult preparation. A fresh approach involves chelation-stabilized bromine(III) species which are conveniently prepared by electro-oxidation of parent bromoarenes. The intrinsic Br(III) reactivity can be unlocked in the presence of acids. In this mechanistic study, electrochemical synthesis, redox properties, and chemical reactivity aspects of chelation-stabilized hypervalent bromine(III) species are disclosed.<\/p>\n<p>[\/vc_column_text][\/vc_column][\/vc_row]<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>[vc_row][vc_column][vc_column_text]Mohebbati, N.; Sokolovs, i.; Woite, P.; L\u00f5kov, M.; Parman, E.; Ugandi, M.; Leito, I.; Roemelt, M.; Suna, E.; Francke, R.; Chem-Eur. J. 2022, 28, e202200974. DOI: 10.1002\/chem.202200974<\/p>\n","protected":false},"author":1,"featured_media":4048,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"image","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[43,16],"tags":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/4046"}],"collection":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/comments?post=4046"}],"version-history":[{"count":2,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/4046\/revisions"}],"predecessor-version":[{"id":4088,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/4046\/revisions\/4088"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media\/4048"}],"wp:attachment":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media?parent=4046"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/categories?post=4046"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/tags?post=4046"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}