{"id":4154,"date":"2023-03-23T15:23:03","date_gmt":"2023-03-23T13:23:03","guid":{"rendered":"https:\/\/ospt.osi.lv\/?p=4154"},"modified":"2023-04-17T14:22:36","modified_gmt":"2023-04-17T12:22:36","slug":"electrochemical-synthesis-of-dimeric-%ce%bb3-bromane-platform-for-hypervalent-bromineiii-compounds","status":"publish","type":"post","link":"https:\/\/ospt.osi.lv\/electrochemical-synthesis-of-dimeric-%ce%bb3-bromane-platform-for-hypervalent-bromineiii-compounds\/","title":{"rendered":"43. Electrochemical Synthesis of Dimeric \u03bb3-Bromane: Platform for Hypervalent Bromine(III) Compounds"},"content":{"rendered":"<div class=\"wpb-content-wrapper\"><p>[vc_row][vc_column][vc_column_text]Sokolovs, I.; Suna, E.; <em>Org. Lett.<\/em> <strong>2023<\/strong>, <em>25<\/em>, 2047\u20132052. DOI: <a title=\"Electrochemical Synthesis of Dimeric \u03bb3-Bromane: Platform for Hypervalent Bromine(III) Compounds\" href=\"https:\/\/doi.org\/10.1021\/acs.orglett.3c00405\" target=\"_blank\" rel=\"nofollow noopener\">10.1021\/acs.orglett.3c00405<\/a><\/p>\n<p><!--more--><\/p>\n<h4>Abstract<\/h4>\n<p style=\"text-align: justify;\">A straightforward and scalable approach to a previously unreported class of cyclic hypervalent Br(III) species capitalizes on the anodic oxidation of aryl bromide to dimeric benzbromoxole that serves as a versatile platform to access a range of structurally diverse Br(III) congeners such as acetoxy-, alkoxy-, and ethynyl-\u03bb<sup>3<\/sup>-bromanes as well as diaryl-\u03bb<sup>3<\/sup>-bromanes. The synthetic utility of dimeric \u03bb<sup>3<\/sup>-bromane is exemplified by photoinduced Minisci-type heteroarylation reactions and benzylic oxidation.<\/p>\n<p>[\/vc_column_text][\/vc_column][\/vc_row]<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>[vc_row][vc_column][vc_column_text]Sokolovs, I.; Suna, E.; Org. Lett. 2023, 25, 2047\u20132052. DOI: 10.1021\/acs.orglett.3c00405<\/p>\n","protected":false},"author":1,"featured_media":4155,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"image","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[43,16],"tags":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/4154"}],"collection":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/comments?post=4154"}],"version-history":[{"count":3,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/4154\/revisions"}],"predecessor-version":[{"id":4166,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/posts\/4154\/revisions\/4166"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media\/4155"}],"wp:attachment":[{"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/media?parent=4154"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/categories?post=4154"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ospt.osi.lv\/wp-json\/wp\/v2\/tags?post=4154"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}